The amide bond in L,L-and L,m-chloropropionylalanine methyl ester is shown to be trans by molar polarization and infrared spectroscopy. In these dipeptide diastereoisomer analogues, therefore, differences in physical properties, i.e., melting points, crystalline forms, gas chromatographic mobilities
The Conformational Characteristics of Dipeptides
β Scribed by Tonelli, A. E.; Brewster, Anne I.; Bovey, F. A.
- Book ID
- 126048273
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 306 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0024-9297
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Integral equation theory is applied to the determination of the intramolecular potential of mean force for the glytine dipeptide, N-acetyl glycyl-N-methylamide, in aqueous solution. The solvated free energy for the dipeptide as a function of the dihedral angles + and 4 (Ramachandran plot) is determi
A compendium of compounds designed as dipeptide mimetics was collected from the literature. Conformational space available to these molecules was evaluated to obtain distance and torsion angle parameters to aid in selection of mimetics for specific target peptides or to explore diversity strategies.