The conformation of N-nitroso-N-methylaniline from microwave spectroscopy
โ Scribed by W. Caminati; A.G. Giumanini
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 520 KB
- Volume
- 162
- Category
- Article
- ISSN
- 0022-2860
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The microwave spectrum of a third conformer (T2t) of \(N\)-methyl ethylenediamine has been assigned using a free-jet millimeter-wave spectrometer in the frequency range \(60-78 \mathrm{GHz}\). T2t has an intermediate energy with respect to those of two conformers ( \(T 1\) and \(T 2 g\) ) previously
The acidity constants of both 2 and E conformational isomers of five N-nitroso-N-alkyl-ol-amino acids, ON-N(Rl)-CH(Rz)-COOH, are determined by the observation of selected pH titrated 'H NMR signals. For two glycine derivatives (1