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Relationships between the acidity of the Z and E isomers of N-Nitroso-N-alkyl-α-amino acids and their conformations

✍ Scribed by Bogdan Liberek; Jerzy Ciarkowski; Krystyna Plucińska; Krystyna Stachowiak


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
441 KB
Volume
18
Category
Article
ISSN
0749-1581

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✦ Synopsis


The acidity constants of both 2 and E conformational isomers of five N-nitroso-N-alkyl-ol-amino acids, ON-N(Rl)-CH(Rz)-COOH, are determined by the observation of selected pH titrated 'H NMR signals. For two glycine derivatives (1


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