The configuration of β-halogenoenamines. The use of a new procedure for NOE measurements
✍ Scribed by Pierre Granger; Stella Chapelle; Jean-Marie Poirier
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 380 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The configurations of 16 different β‐halogenoenamines have been determined using the proton NOE effect, and the same results were obtained as when the ^2^J(CH) coupling constants were used. A new procedure called the ‘repetitive shift frequency’ is presented for the NOE determinations which allows better reproducibility and improves the precision.
📜 SIMILAR VOLUMES
The stereochemistry of the 1-methyl-3-aryltetrahydroisoquinoline ( 2 ) was previously misassigned. Application of NOE difference spectroscopy has Fhown that its correct configuration is the ~na~h-l-methy1-3-(3,4-dirnethoxyphenyl)- S-bromo-7-methoxy-8-hydroxy-1,2,3,4-tetrahydroisoquinoline,
## Abstract A novel procedure for the study of the biodegradation kinetics of styrene is proposed in this paper. Microbial growth tests in the presence of styrene were performed using suspensions of microorganisms prepared from samples of filter bed material. This material had been directly withdra