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The condensation of 2,6-dimethylphenol with glyoxal and with benzil

✍ Scribed by J. C. Mcgowan; Miss Janet M. Anderson; Miss Nancy C. Walker

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
316 KB
Volume
83
Category
Article
ISSN
0165-0513

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Condensation of glyoxal with triethylenetetraamine. Stereochemistry, cyclization and deprotection
✍ Gwénaëlle Hervé; Hélène Bernard; Nathalie Le Bris; Michel Le Baccon; Jean-Jacque 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 203 KB

A mixture of bis-aminal isomers was obtained from aqueous glyoxal-triethylenetetraamine condensation. The irreversible isomerization of the species was observed and a new synthesis of cyclen proposed.