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The complex formation and kinetics in the cleavage of butyl ethers with n-butyllithium

โœ Scribed by Yu. N. Baryshnikov; G. I. Vesnovskaya


Book ID
112363243
Publisher
Springer
Year
1973
Tongue
English
Weight
375 KB
Volume
6
Category
Article
ISSN
0040-5760

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The boron triiodide-N,N-diethylaniline complex, generated in situ from borane:N,N-diethylaniline and iodine cleaves ethers and regenerates carbox-aldehydes from the corresponding geminal diacetate derivatives under mild conditions in good yields. Recently a simple procedure for the preparation of a