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Cleavage of ethers and geminal diacetates using the boron triiodide-N,N-diethylaniline complex

โœ Scribed by Chatla Narayana; Seetharamaiyer Padmanabhan; George W. Kabalka

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
128 KB
Volume
31
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The boron triiodide-N,N-diethylaniline complex, generated in situ from borane:N,N-diethylaniline and iodine cleaves ethers and regenerates carbox-aldehydes from the corresponding geminal diacetate derivatives under mild conditions in good yields.

Recently a simple procedure for the preparation of alkyl and alkenyl iodides in good yields using boron triiodide-N,N-diethylaniline complex and

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