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The comparative activity of mono- and disilacyclobutanes in the reaction with hydrogen chloride

✍ Scribed by N. S. Nametkin; É. D. Babich; V. N. Karel'skii; V. M. Vdovin


Book ID
112422239
Publisher
Springer
Year
1971
Tongue
English
Weight
274 KB
Volume
20
Category
Article
ISSN
1573-9171

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The reaction of sulfoxides with hydrogen
✍ R.H. Rynbrandt 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 128 KB

The reversible formation of sulfodichloride intermediates (&,) has been proposed to explain the RlR2SO + 2HCl&lR2SC123 + Ii20 (Eq. 1) 1 s racemization of optically active sulfoxides by hydrogen chloride in organic solvents (Eq. 1). 1,2 Mislow' h8S suggested that the symmetrization of the sulfodic