The reaction of sulfoxides with hydrogen
โ
R.H. Rynbrandt
๐
Article
๐
1971
๐
Elsevier Science
๐
French
โ 128 KB
The reversible formation of sulfodichloride intermediates (&,) has been proposed to explain the RlR2SO + 2HCl&lR2SC123 + Ii20 (Eq. 1) 1 s racemization of optically active sulfoxides by hydrogen chloride in organic solvents (Eq. 1). 1,2 Mislow' h8S suggested that the symmetrization of the sulfodic