Reaction of silanols with hydrogen chloride
β Scribed by K. K. Popkov
- Book ID
- 104837439
- Publisher
- Springer US
- Year
- 1970
- Tongue
- English
- Weight
- 332 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0021-9037
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π SIMILAR VOLUMES
The reversible formation of sulfodichloride intermediates (&,) has been proposed to explain the RlR2SO + 2HCl&lR2SC123 + Ii20 (Eq. 1) 1 s racemization of optically active sulfoxides by hydrogen chloride in organic solvents (Eq. 1). 1,2 Mislow' h8S suggested that the symmetrization of the sulfodic
Primary and q econdery alkyl isocyanides and phenyl isocyanide react with bydrogwn chloride to compounds the structure cf which waa proved, several years ago, to be Ia-b (1). This reaction is the only hewn example of oligomerization of isocyanides by acid species where C-N-addition haa been proved;