The collisional quenching of O(21D2) by COCl2, COFCl and COF2 using atomic absorption spectroscopy in the vacuum ultraviolet
β Scribed by I.S. Fletcher; D. Husain
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 544 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0047-2670
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π SIMILAR VOLUMES
Time-resolved atomic absorption spectroscopy in the vacuum ultraviolet has been employed to monitor electronically excited oxygen atoms, 0(2\*D2), following their generation by the flash photolysis of ozone in the Hartley band region. We report the first values for the absolute second-order rate con
## Abstract Electronically excited oxygen atoms O(2^1^__D__~2~) have been generated by the pulsed irradiation of ozone in the Hartleyβband continuum and monitored photoelectrically in absorption by timeβresolved attenuation of atomic resonance radiation at Ξ» = 115.2 nm [O(3^1^__D__~2~Β°) β O(2^1^__D
Abstraci
The first absolute rate measurerr,ents for the collisional quenching of the electronically excited oxygen atom, O(2 ' D2 1, by the atmospherically important fluorocarbons, CF2C12 and CFC13, are reported. O(2 ' D2) was generated by the repetitive pulsed irradiation of 03 in the Hartley-band continuum
EIectronicalJy excited oxygen atoms, O(2lD23, generated by the pulsed irradiatkn of ozone in the Hartley continuum, have been observed by bsorption spectroscopy using time-resolved attenuation of resonance radiation in the vacuum ultra-violet (O(31D2$41(21D ) 2 , h 115.2 nm). The concentration profi