Relaxation rates for 02('&+) by nonradiative pathways have been determined using the fast-flow technique. 02 ('\3,+) is formed from 0 2 ( l A g ! by an energy pooling process. 02('AK) is generated by passing purified oxygen through a microwave discharge. Oxygen atoms are removed by distilling mercur
The collisional deactivation of O2(1Δg)
✍ Scribed by I.D. Clark; R.P. Wayne
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 304 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
roughly4 x10-19 a room temperature rate constant of 2.2 f 0.5 L: 10-18 cm3 molec-1 se~-~ by 02 and cm3 molec-1 set-1 by dry air. Deactivation by N2 proceeds at least an order of magnihrde more slowly.
📜 SIMILAR VOLUMES
Rate cocfticicnts for the collisiona! quenching of Of (' a,) by NO and CO, at 2-8 torr and 300 K have been determined. X-NO = (2.48 t 0.23) X lo-" cm3 moleculc~' s-' anzkCOz = (2.56 5 0.12) X IO-" cm3 moleculc~ s-l.
## The dextikation of singlet o\>_rcn O~('A,) on a gold surface and its chan:c due to temperature variation and water \apour addition hate hcrn imestigated in a flow system.
VibrationaII of mixtures of $6 excited 160190(3~~) has been observed at short delay times during the flash photoIysia 03 and 1602. This s !Y an 1802 molecule, indicating that 02( ties can only be formed by the reaction of an 160(lD) atom with C &R,O ia a product of the collisiocaI deactivation of O(