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The cobalt(I) coenzyme B12 model complex [2,10-diethyl-3,9-dimethyl-1,4,8,11-tetraazaundeca-1,3,8,10-tetraene-1,11-diolato(1–)](triphenylphosphine)cobalt(I)

✍ Scribed by Weakley, T. J. R. ;Marks, J. ;Finke, R. G.


Book ID
114511217
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
342 KB
Volume
50
Category
Article
ISSN
0108-2701

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2,8-Dimethoxy-4,10-dimethyl-1,3,7,9-tetr
✍ Bhuiyan, M. Delower H. ;Jensen, Paul ;Try, Andrew C. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 488 KB

In the molecule of the title compound, C~19~H~18~N~6~O~10~, the 2,8-dimethoxy-4,10-dimethyl-1,3,7,9-tetranitro analogue of Tröger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. The hinge angle of the molecule, measured as the dihedra