๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The cobalt transformation

โœ Scribed by C.R Houska; B.L Averbach; M Cohen


Publisher
Elsevier Science
Year
1960
Weight
933 KB
Volume
8
Category
Article
ISSN
0001-6160

No coin nor oath required. For personal study only.

โœฆ Synopsis


The f.c.c. + h.c.p. transformation in cobalt powder(equilibrium temperature = 417ยฐC) has been studied by X-ray methods and correlated with the density of stacking faults in both phases. Only the h.c.p. phase is present in the cold-worked powder. The line broadening due to local strains and small particle sizes can be essentially removed by annealing at 3OO"C, leaving a residual broadening that permits a quantitative determination of the density of random growth and deformation faults. The latter are present in smaller numbers than the growth faults, and are more readily removed by recovery treatments. When the h.c.p.phase is generated from the f.c.c. phase by cooling through the allotropic transformation range, two types of faulted regions become evident: region 1 contains only deformation faults, and region 2 contains both deformation and growth faults. It is suggested that region 1 constitutes the first part of the h.c.p. phase to form on cooling, while region 2 represents the latter part of the transformation. Approximately 25-30 per cent of the parent f.c.c. phase is retained at room temperature under these conditions. Faulting in the f.c.c. phase can be detected with some assurance only after the cooling transformation is underway, but the extent of such faulting is small compared to that in the h.c.p. phase. The observed faulting in both phases is produced mainly by the allotropic transformation, and is not inherited from the parent phase. The faulting generated in the parent phase by the cooling transformation can be partly removed by holding at subcritical temperatures; it is thought that this relaxation process removes barriers to the f.c.r. + h.c.p. transformation and is responsible for the small increments of the h.c.p. phase which form isothermally in the same temperature range. An analysis of the broadening effects in the various diffraction lines suggests that the stacking faults do not terminate within the crystallites or subgrains, but extend to the boundaries. No evidence is found to signify any reversible extension or contraction of the faulting with changing temperat,ure; that is, the faults observed are not in thermodynamic balance. LA TRANSFORMATION DU COBALT Les uuteurs ont Btudie, par des methodes de rayons X, la transformation c.f.c. + hx. de cobalt en poudre (temperature d'equilibre = 417'C). 11s ont egalement Btudii! la densite des fautes d'empilement dans les deux phases de la transformation. Seule la phase h.c. existe dans la poudre d&for&e a froid. L'elargissement des raies dir a des deformations locales et aux dimensions faibles des particules, disparait par un traitement a 300ยฐC. L'elargissement residue1 permet une determination quantitative de la densite des fautesde croissance et de deformation. Ces dernieres sont mains nombreuses que les fautes de croissance et son plus facilement Bliminites par des traitements de revenu. Lorsque la phase h.c. se forme au depart de phase c.f.c. par refroidissement au travers de la transformation allotropique, deux types de regions imparfaites apparaissent: la region 1 contient uniquement des fautes de deformation et la region 2 contient. * This paper is based on a doctorate thesis presented in January 1957 by C. R. Houska to the Department of Metallurgy at


๐Ÿ“œ SIMILAR VOLUMES


On the phase transformation of cobalt
โœ W. Bollmann ๐Ÿ“‚ Article ๐Ÿ“… 1961 ๐Ÿ› Elsevier Science โš– 547 KB

## On the phase transformation of cobalt* A lot of work has been done on the phase transformation of cobalt from the face-centred cubic structure above 417ยฐC to the hexagonal close packed below this temperature.

The cubic-hexagonal transformation in si
โœ P Gaunt; J.W Christian ๐Ÿ“‚ Article ๐Ÿ“… 1959 ๐Ÿ› Elsevier Science โš– 574 KB

Kinetic and crystallographic observations on the natural and stress-induced transformations in single crystals of cobalt and cobalt-nickel alloys have oonhrmed the martensitic nature of the change. The shape deformation has been measured for the stress-induced transformation in alloys; the habit pla