New spectroscopic absorption and luminescence data for the ions M(bpy)~ + @I = Fe, Ru, Os) provide the basis for a theoretical model of the electronic structure of these ions. An important aspect of the model is the essential localization of the triplet states, in contrast to the singlet states whic
The circular dichroism of the charge-transfer bands of M(bpy)2+3 (M = Re, Ru, Os)
β Scribed by James Ferguson; Fritz Herren; George M. McLaughlin
- Book ID
- 107732930
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 358 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
Reductive electrocrystallization at a constant current density (1 1 .0-11.5 pA/cm2) of millimolar solutions of [ M ( ~~Y ) , ] ( P F ~) ~, where M = Fe, Ru, or Os, and bpy = 2,T-bipyridine in acetonitrile containing 0 . 1 ~ Bu4NPF, results in the formation of dark crystals on the Pt cathode. The cry
The magnetic circular dichroism (MCD) and circular dichroism (CD) of Ru(bpy)F (RBY) doped in siqzleaystal Zn(bpy)s(BF& (BF) and dissolved in poly(vinyl alcohol) (PVA) are presented, as well as the MCD of a number of related materials in PVA. Two A terms of opposite sign are observed in the singlet r