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The chemistry of trifluorosulfinic acid and its derivatives

โœ Scribed by H.W. Roesky; G. Holtschneider

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
288 KB
Volume
7
Category
Article
ISSN
0022-1139

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โœฆ Synopsis

The preparation of NaS02CF3, KS02CF3 and AgS02CF3 from HS02CF3 and the corresponding carbonates is described. CF3S(0)N[Si(CH3)3]2 or CF3S(0)NHSi(CH3)3 react with SOC12 to form CF3S(0)N=S=0. A compound with two sulfur atoms in oxidation state +4. The reaction products of CF3S(0)NC0 with CHSOH, CHICOOH, (CH3)2NH, (C2H5)2NH, CF3S(0)NH2 and CF3S02NH2 are reported. In contrast to N[Si(CH3)3]3 the tin analog reacted with CF3S(0)C1 to CF3S(0)OSn(CH3)3. CF3S(0)NHC(O)OCH3

๐Ÿ“œ SIMILAR VOLUMES

The Chemistry of Nitrous Acid and of its
The Chemistry of Nitrous Acid and of its Derivatives in Liquid Hydrogen Fluoride
โœ Prof. Dr. F. Seel ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 707 KB

The reaction of liquid hydrogen fluoride with nitrous acid, dinitrogen trioxide, dinitrogen tetroxide, and nitrosyl compounds leads to unexpectedly high-boiling liquids which contain nitrosyl fluoride in the form oj-remarkably stable, electrolytically dissociated hydrogen fluoride solvates. Nitrosyl