The Chemistry of Nitrous Acid and of its Derivatives in Liquid Hydrogen Fluoride
โ Scribed by Prof. Dr. F. Seel
- Publisher
- John Wiley and Sons
- Year
- 1965
- Tongue
- English
- Weight
- 707 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
โฆ Synopsis
The reaction of liquid hydrogen fluoride with nitrous acid, dinitrogen trioxide, dinitrogen tetroxide, and nitrosyl compounds leads to unexpectedly high-boiling liquids which contain nitrosyl fluoride in the form oj-remarkably stable, electrolytically dissociated hydrogen fluoride solvates. Nitrosyl fluoride solvated by pure hydrogen fluoride is a new reagent, valuable in fluorine chemistry since it reacts with many elements and compounds to form fluorine derivatives of preparative importance.
๐ SIMILAR VOLUMES
The reaction mechanism of the a, a and a, /3 elimination of hydrogen fluorides from alkyl fluorides has been studied theoretically. For fluoroethane as a reactant, the transition state (1s) optimized at the level of the 6-31~\*\* basis set shows that the Q, /3 elimination proceeds via a four membere