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The chemistry of thujone. VI. Thujone as a chiral synthon for the synthesis of optically active steroid analogues

✍ Scribed by James P. Kutney; Peter Grice; Keith O. Pascoe; Krystyna Piotrowska; Steven J. Rettig; Jerzy Szykula; James Trotter

Publisher
John Wiley and Sons
Year
1982
Tongue
German
Weight
562 KB
Volume
65
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The thujone derived enone 1 is converted in one step to the pentacyclic compound 4. The structure of 4 was determined by X‐ray diffraction analysis. The acid‐catalyzed cyclopropane‐ring opening of 4 and of the model compound 9 are described.

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