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The Chemistry of the Solvated Metal Chelates. I. Thermochemical and Kinetic Studies 1,2

โœ Scribed by Van Tassel, James H.; Wendlandt, Wesley W.

Book ID
126785503
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
450 KB
Volume
81
Category
Article
ISSN
0002-7863

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Kinetic studies for the reaction of R3B3N3R;0-(CO), (R and R ' = Me, Et, n-l+, i-Pr) with tertiary phosphites are reported. The results indicate that steric factors are most important for the rate of ring ligand displacement. There is no correlation between AC' (293 K) and the strength of the borazo