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Metal ion-sulfur(IV) chemistry. 2. Kinetic studies of the redox chemistry of copper(II)-sulfur(IV) complexes

✍ Scribed by Conklin, Martha H.; Hoffmann, Michael R.


Book ID
126087593
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
1023 KB
Volume
22
Category
Article
ISSN
0013-936X

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Kinetics of the simultaneous oxidation o
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## Abstract In the Ni(II)–S(IV)–O~2~ system in the region of pH > 8.4, both Ni(II) and S(IV) are simultaneously autoxidized, and when sulfur is consumed fully NiOOH precipitates. At pH > 8.4, ethanol has no effect on the rate, whereas ammonia strongly inhibits the reaction when pH > 7.0. The kineti