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Redox chemistry of the polyimine complexes of manganese(II), -(III), and -(IV) in acetonitrile

โœ Scribed by Morrison, Mark M.; Sawyer, Donald T.

Book ID
121409326
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
645 KB
Volume
17
Category
Article
ISSN
0020-1669

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Redox kinetics of metal complexes in non
Redox kinetics of metal complexes in nonaqueous solutions. V. Kinetics and mechanism of the iron (II) reduction of the acetylacetonates of manganese (III) and cobalt (III) in acetonitrile
โœ Roland Schmid; Valentin N. Sapunov ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 737 KB

The electron transfer step of the reduction of Mn(acac)s and Co(acac)s by Fe(I1) in acetonitrile is preceded by the one-ended dissociation of an acac ligand and the formation of a binuclear bridged complex. After the electron transfer has taken place through the bridging ligand, the complex dissocia