The Chemistry of L-Sorbose
✍ Scribed by Ilhem Zebiri; Sébastien Balieu; Arnaud Guilleret; Romain Reynaud; Arnaud Haudrechy
- Book ID
- 102830041
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 651 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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✦ Synopsis
Abstract
Despite the fact that L‐sorbose has been widely used for the synthesis of vitamin C at an industrial level, its use in organic synthesis remains rare. However, a survey of the chemical literature shows that this unusual sugar can be transformed into interesting derivatives.
📜 SIMILAR VOLUMES
In previous communications, we reported that the acetonation of L-sorbose (I) with acetone dialkyl ketals afforded IIa-VIIa (1,2) by a different mode than the acetonatlon with acetar.:, (3). We have since investigated the reaction mechanisms of the former acetonation and concluded that the reaction
Aceton-xyluronsaure-methylesterl) Torn Sdp. n,m 181O werden mit 20 g ganz trockenem Silberosycl und 14 g Nethyljoditl acht Stunden auf dem Wasserbade unter Ruckfluss erhitzt. Danach wird weitere acht Stunden mit neuen 30 g Silberoxyd und 1 4 g Methyljodid erhitzt. Nach beendeter Reaktion wird mit vi