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The chemistry of cyclopentadienyl-ruthenacyclopentatrienes: novel carbon monoxide and isocyanide insertion reactions in [η5-C5H5)Ru(η4-C5Ph2H2NBut)Br]

✍ Scribed by Michel O. Albers; Dirk J.A. De Waal; David C. Liles; David J. Robinson; Eric Singleton

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
301 KB
Volume
326
Category
Article
ISSN
0022-328X

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Cyclopentadienyl and its derivatives (Cp ligands) are among the most extensively utilized p ligands in organometallic chemistry. In most organometallic reactions of transitionmetal complexes, the h 5 -Cp ligand plays the role of a spectator that stays tightly bound in h 5 fashion to the metal center