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The chemistry of cycloheptatrienyl complexes of molybdenum and tungsten: synthesis and redox chemistry of some phosphine- and phosphite-substituted halide and acetonitrile derivatives

โœ Scribed by Caroline Bitcon; Roy Breeze; Patrick F. Miller; Mark W. Whiteley

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
1015 KB
Volume
364
Category
Article
ISSN
0022-328X

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The oxidation of organic compounds by hydrogen peroxide, catalysed by transition metal derivatives, e.g. V(V), Mo(V1) and W (VI) complexes, involves the formation of peroxometal complexes. These are much more efficient oxidants than hydrogen peroxide so that the catalysed reactions are of remarkable