An important series of catalytic reactions involve some of the intermediates and pathways discussed in previous chapters. Alkene metathesis (Eq. 12.1), now gaining wide acceptance in organic and polymer synthesis, goes via metal carbene intermediates. Alkene polymerization, a key modern development
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The Organometallic Chemistry of the Transition Metals (Crabtree/The Organometallic Chemistry) || Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions
โ Scribed by Crabtree, Robert H.
- Publisher
- John Wiley & Sons, Inc.
- Year
- 2005
- Weight
- 298 KB
- Edition
- 4
- Category
- Article
- ISBN
- 0471662569
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In this chapter we continue our survey of the different types of ligand by looking at cases in which the ฯ electrons of an unsaturated organic fragment, rather than a lone pair, are donated to the metal to form the M-L bond. ### 5.1 ALKENE AND ALKYNE COMPLEXES In 1827, the Danish chemist Zeise obt
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