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The chemistry of cycloheptatriene. Part XVI . Sigmatropic shifts of hydrogen in methylcycloheptatriene

✍ Scribed by A. P. Ter Borg; H. Kloosterziel

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
396 KB
Volume
88
Category
Article
ISSN
0165-0513

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The chemistry of cycloheptatriene: Part
The chemistry of cycloheptatriene: Part VIII: Transannular 1-5 shifts of hydrogen in phenylcycloheptatriene
✍ A. P. ter Borg; H. Kloosterziel πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 714 KB

## Abstract 7‐Phenylcycloheptatriene‐1,3,5 rearranges on heating to a mixture of the 3‐, 1‐ and 2‐isomers. These are formed in the order indicated by successive trans‐annular 1‐5 shifts of hydrogen. The isomerization of the 7‐ to the 3‐isomer, by which the trienic and aromatic systems enter into co