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The chemistry of cycloheptatriene, part XIII.: Thermal fragmentation of 7-dimethylaminocycloheptatriene to benzene and dimethylaminocarbene

✍ Scribed by A. P. Ter Borg; E. Razenberg; H. Kloosterziel

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
130 KB
Volume
85
Category
Article
ISSN
0165-0513

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The chemistry of cycloheptatriene: Part
The chemistry of cycloheptatriene: Part IX: Thermal interconversion of 2,7- and 2,3-dihydrotropone by transannular 1-5 shifts of hydrogen
✍ A. P. ter Borg; H. Kloosterziel 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 352 KB

## Abstract 2,7‐Dihydrotropone upon heating at 60‐100deg; isomerizes (partly) to the 2,3‐isomer. Kinetic data: order of the reaction, influence of solvent and entropy of activation, point to a mechanism involving an intramolecular 1‐5 shift of hydrogen in this cycloheptadiene derivative.