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The chemistry of cycloheptatriene: Part IX: Thermal interconversion of 2,7- and 2,3-dihydrotropone by transannular 1-5 shifts of hydrogen

✍ Scribed by A. P. ter Borg; H. Kloosterziel

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 352 KB
Volume: 82
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19630821208

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✦ Synopsis

Abstract

2,7‐Dihydrotropone upon heating at 60‐100deg; isomerizes (partly) to the 2,3‐isomer. Kinetic data: order of the reaction, influence of solvent and entropy of activation, point to a mechanism involving an intramolecular 1‐5 shift of hydrogen in this cycloheptadiene derivative.

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