The chemistry of 2-hydroxy-2,4,6-cyclooctatrienone (1,7-π-homotropolone)
✍ Scribed by Yoshio Kitahara; Masaji Oda; Shōichi Miyakoshi; Shōzō Nakanishi
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 219 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
It is of interest to which the chemical properties of 2-hydroxy-2,4,6-1 cyclooctatrienone (1,7-n-homotropolone) 1 have likeness, 2,4,6-cyclooctatrienone 2 or tropolone here to report the 3 -* The photochemical chemistry of 1. behavior of 1 resembles 2.
📜 SIMILAR VOLUMES
In the preceding paper, we reported the synthesis of 2-hydroxy-2,4,6-cyclooctatrienone 1. which we considered to be called 1,7-\*-homotropolone.
## Abstract Aus den Tetralonen I und XIII wurden auf zwei verschiedenen Wegen die Phenanthrene VIII bzw. VIIIb und XVI hergestellt. Versuche zur Synthese von Orchinol (2,4‐Dimethoxy‐7‐hydroxy‐9,10‐dihydrophenanthren) scheiterten in der partiellen Dehydrierung der tricyclischen Ketone X und XI und f
The new chiral backbones (R)-(+)-and S-(-)-2-amino-2%-hydroxy-6,6%-dimethyl-1,1%-biphenyl and (R)-(+)-and (S)-(-)-2-amino-2%-hydroxy-4,4%,6,6%-tetramethyl-1,1%-biphenyl were synthesized from o-methylaniline and 2,4-dimethyl-aniline respectively in seven steps. A new resolution method was developed t