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The chemical properties of bimetallic surfaces: bonding between CO and Zn on Ru(001)

✍ Scribed by JoséA. Rodriguez

Publisher
Elsevier Science
Year
1993
Weight
507 KB
Volume
289
Category
Article
ISSN
0167-2584

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The role of σ-donation in the bonding of molecular nitrogen on clean and modified Ru(001) surfaces
✍ R.A. Depaola; F.M. Hoffmann 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 424 KB

We demonstrate that the adsorption of molecular nitrogen on modified Ru(OO1) is, in contrast to CO adsorption, largely governed by its acharge donation to the metal, which can be promoted by coadsorbed oxygen. Preadsorbed potassium inhibits nitrogen adsorption for 6K > 0.08, thus enabling us to dete