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The characterization of intermediates in the mitomycin activation cascade: a practical synthesis of an aziridinomitosene

โœ Scribed by Danishefsky, Samuel J.; Egbertson, Melissa.


Book ID
125888047
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
401 KB
Volume
108
Category
Article
ISSN
0002-7863

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An Enantioselective Total Synthesis of (+)-Methyl Pederate. -The key intermediate for theopederins, methyl pederate (IV), is available by a practical route involving the pivotal Pd-catalyzed cyclization of the carbonate (II) as key step. -(TOYOTA, M.;