Structure–reactivity correlations in the
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Enrique A. Castro; María G. Ruiz; José G. Santos
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Article
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2001
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John Wiley and Sons
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English
⚖ 137 KB
The reactions of a series of secondary alicyclic amines with 4-methylphenyl and 4-methoxyphenyl chloroformates are subjected to a kinetic investigation in water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess, pseudo-first-order rate coefficients (k obs ) are found for all reactions. Plot