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The CH3NO bond dissociation energy

✍ Scribed by L. Batt; R. T. Milne

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
166 KB
Volume
5
Category
Article
ISSN
0538-8066

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✦ Synopsis

Early estimates for the C-NO bond dissociation energy in nitrosomethane range from 30 to 57 kcal mole-' [1,2]. Values for D(R-NO) are important in relation to the inhibition, by nitric oxide, of the gas-phase pyrolysis of organic compounds [3,4]. Any nitric oxide inhibition scheme has to consider the ratio of the relative paths to redissociation and isomerization of the nitroso compound, formed by the combination of R and NO, for effective trapping. A convenient route for the determination of D(CH3-NO) is via AHrO(CH3NO) from the equilibrium (l,Z),

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