Resolved flame emission spectra from the reaction of ozone, O 3, with zinc dimethyl, Zn (CH3) 2, and zinc diethyl, Zn (C2Hs)2, in a flow system at about one tort pressure reveal a number of interesting electronically-excited species. The Zn (CHs) 2 + 0 3 flame has a pale blue appearance, characteris
Metal-alkyl bond dissociation energies for (CH3)2Zn, (C2H5)Zn, (CH3)2Cd, and (CH3)2Hg
β Scribed by Robert L. Jackson
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 686 KB
- Volume
- 163
- Category
- Article
- ISSN
- 0009-2614
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## Abstract The reaction of lithium phenyl(trimethylsilyl)methanide with phenyl(trimethylsilyl)methylzinc chlorideβtmeda in the presence of tmeda yields the addition product, a bis(tmeda)βlithium dialkylchlorozincate. The elimination of lithium chloride leads to the formation of a tmeda adduct of b