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The C–D Stretch of Monodeuterated Propargyl Radical (CH2CCD)

✍ Scribed by Wade C. Eckhoff; Charles E. Miller; Charles F. Billera; Paul S. Engel; R.F. Curl

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
245 KB
Volume
186
Category
Article
ISSN
0022-2852

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✦ Synopsis

The high-resolution infrared spectrum of the monodeuterated propargyl radical ( CH 2 CCD ) has been obtained in the region of its acetylenic C -D stretch. Lower state rotational constants were determined for the molecule. The upper state was significantly perturbed making the upper state rotational constants determined much more uncertain.

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