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The cathodic reduction potential of Fe3O4 and the flade potential of iron

โœ Scribed by A. Hickling

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
187 KB
Volume
18
Category
Article
ISSN
0013-4686

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The cathodic reduction of Fe,O,, FeOOH, and Fe,O, in dilute sulphuric acid has been directly investigated using graphite paste electrodes containing the oxides. It has been found that these oxides sustain redox reactions at a high positive potential which is stabilised by the presence of ferrous sul

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An analysis of capacitance potential data of passive iron on the basis of the theory of critical states yields a critical point near the Flade potential EF. The critical point is characterized by a minimal critical thickness of the passive layer of about 1.3 nm at EF, yielding a field strength withi