✦ LIBER ✦

The catalytically active conformation of cyclo-[(S)-His-(S)-Phe] as determined by solid state NMR

✍ Scribed by David Apperley; Michael North; Robert B. Stokoe

Book ID: 103977217
Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 188 KB
Volume: 6
Category: Article
ISSN: 0957-4166
DOI: 10.1016/0957-4166(95)00239-l

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✦ Synopsis

The solid state conformation of the amorphous catalyst cyclo-[(S)-His-(S)-Phe] is

determined by a combination of solid state tH and 13C NMR techniques. The results provide strong evidence in support of the previously proposed mechanism for the asymmetric addition of HCN to aldehydes catalysed by this dipeptide.

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