Metal Clusters as Ligands: Substitution of Fe ions in Fe/Mo/S Clusters by Thiophilic Cu I Ions To Give Clusters with [Cu 4 Mo 2 Fe 2 S 8 ] 4+ and [Cu 5 Mo 3 Fe 4 S 11 ] 6+ Cores
β¦ LIBER β¦
The catalytic oxidation of thiols to disulfides by the cluster [Fe4S4(SR)4]2- and associated ligand effects
β Scribed by Tetsuo Nagano; Kazumasa Yoshikawa; Masaaki Hirobe
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 242 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The cluster (nBu N) [Fe S (SR) 1, the analogue of the active site of nonheme iron-sulfur p ot 4 $ ins, 4 $atal$zed the oxidation of thiols to disulfides extremely and the llgand effects for the catalytic oxidation were investigated.
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