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Cluster synthesis by the reactions of [Cp′2M2S4] with metal complexes (Cp′=Cp and substituted cyclopentadienyl ligands, M=Fe, Ru)

✍ Scribed by Masaaki Okazaki; Masahiko Yuki; Katsuaki Kuge; Hiroshi Ogino

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 264 KB
Volume: 198
Category: Article
ISSN: 0010-8545
DOI: 10.1016/s0010-8545(99)00194-0

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✦ Synopsis

Dinuclear transition-metal sulfur complexes of the type [Cp% 2 M 2 S 4 ] (Cp%=Cp and substituted cyclopentadienyl ligands) have been used as excellent starting materials for building up multinuclear transition-metal sulfur clusters. However, little is known about the versatility of the iron-and ruthenium-containing complexes. This urged us to examine the nature of Cp% 2 M 2 S 4 (M=Fe, Ru). The present review describes the research on homo-and heteronuclear cluster synthesis by the reactions of Cp% 2 M 2 S 4 (M= Fe, Ru) with various transitionmetal complexes.

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