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The catalytic oxidation of dithiols by a semisynthetic enzyme

โœ Scribed by Stewart, Kent D.; Radziejewski, Czestaw.; Kaiser, E. T.

Book ID
127242668
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
550 KB
Volume
108
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Autoxidation of ascorbic acid catalyzed
Autoxidation of ascorbic acid catalyzed by a semisynthetic enzyme
โœ Juris P. Germanas; Emil T. Kaiser ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 430 KB

The semisynthetic enzyme 6 was prepared by alkylation of the cysteine-25 sulfhydryl group of papain with the bipyridine 5 and was shown to stoichiometrically bind copper ion; 7 catalyzed the autoxidation of ascorbic acid derivatives with saturation kinetics approximately 20-fold faster than a model