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The catalysis of some novel polystyrene-supported porphyrinatomanganese(III) in hydroxylation of cyclohexane with molecular oxygen

✍ Scribed by Jin-Wang Huang; Wen-Jie Mei; Jie Liu; Liang-Nian Ji

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
78 KB
Volume
170
Category
Article
ISSN
1381-1169

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The preparation of some polystyrene-supp
The preparation of some polystyrene-supported porphyrinatoiron(III) and their catalysis in hydroxylation of cyclohexane with molecular oxygen
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Some polystyrene-supported porphyrinatoiron( III) with different stereostructure were prepared using a new method and characterized by EA, UV-Vis,IR and EPR. Their catalytic activities in hydroxylation of cyclohexane with molecular oxygen have been found to be high compared with corresponding non-su

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## Ε½ . Ε½ . The hydroxylation of cyclohexane catalyzed by 5,10,15,20-tetraphenylporphyrinatoiron III chloride TPPFeCl with molecular oxygen in various solvents have been preliminarily studied in the case when the catalytic reaction was not carried out in lighttight. The catalytic activity of TPPFeC

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Three iron(III)-metal-free porphyrin dimers linked covalently with a flexible butoxy chain at the paru position of the two phenyl rings have been prepared and characterized. The hydroxylation of cyclohexane catalyzed by these dimers with molecular oxygen under mild condition has been studied prelimi