✦ LIBER ✦

Hydroxylation of cyclohexane catalyzed by porphyrinatoiron(III) with molecular oxygen: the effect of the photochemical stability of porphyrinatoiron(III) in various solvents

✍ Scribed by Jin-Wang Huang; Wei-Zhuang Huang; Wen-Jie Mei; Jie Liu; Shu-Guang Hu; Liang-Nian Ji

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 117 KB
Volume: 156
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(99)00447-1

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✦ Synopsis

Ž .

Ž . The hydroxylation of cyclohexane catalyzed by 5,10,15,20-tetraphenylporphyrinatoiron III chloride TPPFeCl with molecular oxygen in various solvents have been preliminarily studied in the case when the catalytic reaction was not carried out in lighttight. The catalytic activity of TPPFeCl in various solvents was found to increase in the following order: acetone-benzene-methyl-cyanide, which is consistent with the order of the photochemical stability of TPPFeCl in various solvents. It seems these results are helpful to the choice of solvents in the research of the model of cytochrome P450.

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