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The carboxylation of cyclooctatetraene dianion

✍ Scribed by Thomas S. Cantrell


Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
182 KB
Volume
9
Category
Article
ISSN
0040-4039

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Cyclooctatetraene dianion from 1,5-cyclo
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A novel synthesis of cyclooctatetraene dianion from 1,5-cyclooctadiene (1,5-COD) is described. The reaction of the potassium-naphthalene adduct with 1,5-COD proceeds at room temperature over 3 days in heptane/tetrahydrofuran to produce the target compound.

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