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Cyclooctatetraene dianion from 1,5-cyclooctadiene. A synthesis in the presence of naphthalene radical anion

✍ Scribed by Leslie H. Simons; J.J. Lagowski

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 58 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00144-2

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✦ Synopsis

A novel synthesis of cyclooctatetraene dianion from 1,5-cyclooctadiene (1,5-COD) is described. The reaction of the potassium-naphthalene adduct with 1,5-COD proceeds at room temperature over 3 days in heptane/tetrahydrofuran to produce the target compound.

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