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The Carbonylation Reaction of Nitrobenzene to Methyl Phenylcarbamate: Highly Efficient Promoters for the Palladium–Phenanthroline Catalytic System Based on Phosphorus Acids

✍ Scribed by Fabio Ragaini; Carlo Cognolato; Michela Gasperini; Sergio Cenini

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
96 KB
Volume
42
Category
Article
ISSN
0044-8249

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We thank Enichem for financial support and The Dow Chemical Company for the permission to publish these results. We also thank Dr. C. Querci (Polimeri Europa, Istituto Donegani) for helpful discussions.

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Phosphorus acids are excellent promoters for the palladium-phenanthroline catalyzed carbonylation of 2,4-dinitrotoluene to 2,4-toluenedicarbamate. For the first time, all intermediate nitrocarbamates and aminocarbamates have been independently synthesized and their amount after every catalytic react