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The Carbonylation Reaction of Nitrobenzene to Methyl Phenylcarbamate: Highly Efficient Promoters for the Palladium–Phenanthroline Catalytic System Based on Phosphorus Acids

✍ Scribed by Fabio Ragaini; Carlo Cognolato; Michela Gasperini; Sergio Cenini

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
95 KB
Volume
115
Category
Article
ISSN
0044-8249

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✦ Synopsis

We thank Enichem for financial support and The Dow Chemical Company for the permission to publish these results. We also thank Dr. C. Querci (Polimeri Europa, Istituto Donegani) for helpful discussions.

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✍ Michela Gasperini; Fabio Ragaini; Chiara Cazzaniga; Sergio Cenini 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB

Phosphorus acids are excellent promoters for the palladium-phenanthroline catalyzed carbonylation of 2,4-dinitrotoluene to 2,4-toluenedicarbamate. For the first time, all intermediate nitrocarbamates and aminocarbamates have been independently synthesized and their amount after every catalytic react