The capillary flow of silicones
β Scribed by Donald L. Johnson; Eric Baer
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- English
- Weight
- 404 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
The nonβNewtonian flow of silicone fluids in capillaries was investigated with special emphasis on the viscoelastic nature of entrance and exit effects. At low pressures the power law was obeyed, while at high pressures considerable deviations were observed, particularly with short capillaries. For capillaries with large lengthβtoβradius ratios, the flow index and consistency approached the Newtonian values. Entrance effects were successfully analyzed by the method proposed by Bagley. At low shear stresses the end correction was dependent only on the geometry of the apparatus. An elastic contribution to the end correction was observed only at high shear stress, indicating a relatively mild viscoelastic behavior. Additional evidence indicating small elastic effects was obtained from swelling measurements of capillary jets.
π SIMILAR VOLUMES
## Enhancement of electroosmotic flow in capillary electrochromatography A major impediment to enhancing the speed of separation in capillary electrochromatography (CEC) is the upper limit on the electroosmotic flow (EOF) velocity by the maximal zeta potential of the chromatographic surface. Here,