Rate constants have been measured in aqueous solutions for the reactions of the carbonate radical, COs'-, with several saturated alcohols and one cyclic ether as a function of temperature. Arrhenius pre-exponential factors ranged from 2 X lo8 to 1 X lo9 e mol-' s-l and activation energies ranged fr
The capacity of an α-nitroalkyl radical for hydrogen abstraction
✍ Scribed by T.A.B.M. Bolsman; J.W. Verhoeven; Th.J. de Boer
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 385 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
Rate constants have been determined for the reactions of SO4with a series of alcohols, including hydrated formaldehyde. The SO,radical was produced by the laserflash photolysis of persulfate, Sz02-. Rate constants for the reactions of SO4with alcohols range from 1.0 x lo7 for methanol to 3.4 x 10' M
Rate constants have been determined for the reactions of SO4with a series of alkanes and ethers. The SO, radical was produced by the laser-flash photolysis of persulfate, SZO: -. For methane, only an upper limit of 1 x lo6 M-' s-\* could be determined. For ethane, propane, and 2-methylpropane, rate
## Abstract Measurements of rates of oxygen absorption and steady‐state peroxy radical concentrations for the autoxidation of tetralin in the presence of __tert__‐butyl hydroperoxide have shown that the rate constant for reaction of the __tert__‐butylperoxy radical with tetralin at 60°C is approxim