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THE C 4 -SACCHARINIC ACIDS. I. THE RESOLUTION OF dl- 2,3-DIOXYBUTYRIC ACID INTO THE OPTICALLY-ACTIVE COMPONENTS. THE DERIVATIVES OF THESE ACIDS.

โœ Scribed by Glattfeld, J. W. E.; Miller, George E.


Book ID
126989022
Publisher
American Chemical Society
Year
1920
Tongue
English
Weight
673 KB
Volume
42
Category
Article
ISSN
0002-7863

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Synthesis and optical resolution of dl-c
โœ Osamu Tamura; Masaru Hashimoto; Yuko Kobayashi; Tadashi Katoh; Kazuhiko Nakatani ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 276 KB

The title synthesis was accomplished by featuring highly cis-selective cyclopropanation of an Nvinylcarbamate with zinc-monofluorocarbenoid followed by deprotection of the formed N-(cis-2fluorocyclopropyl)m&amate. Optical resolution of~-cis-2-~~ro~clopropyhnrinc was also achiewd by employing lmenthy