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The breakdown of passive films on active metal anodes by halide ions in oxidizing molten salts

✍ Scribed by M. H. Miles


Publisher
Springer
Year
1981
Tongue
English
Weight
655 KB
Volume
11
Category
Article
ISSN
0021-891X

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Anodic oxide films on titanium formed in
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Titanium was oxidized anodically in molten sodium nitrite, and sodium nitrite containing 1 mol-% sodium peroxide, at constant cd at 315Β°C. The anodic oxide film showed rectitication, and photocurrent and photovoltage. From these results and the measurements of capacitance of the film, the flhn is pr

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The effects of formation conditions, especially the electrolyte, on the non-stoichiometry of the anodic oxide films of titanium have been studied. The electrolytes were molten sodium nitrite, molten sodium nitrate and molten mixture of these salts and sodium peroxide, which was used to change the ox